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Glowing glass
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In the present case I evacuated the discharge tube to the fullest extent possible using my new (rotary vane) vacuum pump, whose lowest residual pressure is rated at 2 Pa (0.02 mbar). The resulting plasma excited at 15 kV is so tenuous that it is not even clearly visible, but its energetic electrons and photons do excite the glass vessel, which radiates a nice blue glow. Like in other tubes shown in this series, the gas pressure and composition changes gradually due to a plasma-driven cleanup process: molecules are dissociated by energetic electrons and the resulting atoms react with the tube materials. As a result, the glass fluorescence diminishes over time as there are less and less molecules present in the volume. I should be able to fix that when I'll switch to argon and helium fills later this year (or early next).
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I should not take such a chance anyway, next time I'll use a Geiger counter to check this tube (better be sure than sorry). I've once seen the effect of an accidental X-ray emission from a vacuum valve (it occurred for a brief moment when the incandescent cathode was switched off while the HV was still applied) and I remember seeing the glass glowing a eerie greenish color, not the blue light see here, hence my conclusion that the glass excitation comes primarily from the tenuous plasma, but I better check that to be sure.